河南省许昌市矿山地质环境问题分区评价研究     

宋高举  黄继超  张公  王帅 《地质与资源》2022,31(2):221-227

以斜坡单元作为评价单元, 通过建立区域地质环境背景、资源损毁和地质灾害3要素评价指标体系, 对各评价指标进行量化, 赋予权重, 利用GIS图层叠加分析, 对许昌市矿山地质环境进行分区评价. 分区结果与现状调查结果较为一致, 验证了此方法的实用性, 为规划与治理该地区矿山环境地质问题提供参考依据.  相似文献   

安徽五河地区天井湖铅金矿床原生晕地球化学特征     

张建明  肖涛  张家嘉 《江苏地质》2021,45(3):247-253

系统采集安徽五河地区天井湖铅金矿床16个钻孔的岩石、矿石样品,选择钻孔数量较多、矿体连续性较好的90勘探线为研究对象,绘制原生晕地球化学剖面图,建立了5个铅金矿体的原生晕轴向分带序列,结合相关指示元素的分布规律,对铅金矿体的深部延伸进行预测。通过研究,总结出矿床前缘晕元素为As,主成矿元素为Au、Pb,尾晕元素为Bi。根据矿体原生晕特征和相关指示元素的分布规律,推测该矿床为多期成矿的中低温热液矿床,预测Ⅰ号和4号矿体的延伸方向及ZK9004、ZK9006孔深部As异常的延伸方向有盲矿体存在。  相似文献   

青岛连三岛地区“荆山岩群”高压变质岩的变质时代和变质演化特征     

郜源  曹玉亭  王淞杰  李旭平  孔凡梅 《岩石学报》2021,37(5):1347-1371

青岛连三岛地区原划为古元古界荆山岩群中出露各类片岩、片麻岩。本文在前人研究的基础上,对连三岛地区出露的含榴黑云母斜长片麻岩、含榴云母片岩和含榴黑云母钾长片麻岩,进行详细的岩相学和矿物化学研究,确定其变质温压条件及其P-T演化轨迹,并采用LA-ICP-MS锆石U-Pb定年,获得了3个样品的原岩时代和变质时代,为全面深入认识其变质属性提供了进一步的重要依据。根据岩相学和矿物化学成分可以识别出两期矿物组合:第一期(峰期变质阶段)为Grt1+Kfs+Aln+Ph+Qtz;第二期(退变质阶段)为Grt2+Pl+Ep+Bt+Qtz;依据多硅白云母Si压力计、锆石Ti温度计以及GB-GBPQ矿物温压计,确定其峰期变质和退变质的温压条件分别为T=600～817℃、P=2.4～2.6GPa和T=431～456℃、P=0.48～0.82GPa。结合白云母部分熔融现象,上述两个变质阶段构成了一个折返早期升温降压,后穿过多硅白云母熔融反应线,最后降温降压的顺时针型演化的P-T轨迹。CL图像显示3个样品的锆石均具有典型的岩浆核-变质边结构;结合LA-ICP-MS锆石原位微区U-Pb定年和微量元素分析,3个样品分别获得了769～756Ma、～223Ma和213～216Ma三组年龄,分别与苏鲁造山带其他高压-超高压变质岩的新元古代原岩时代(700～800Ma)、峰期变质时代(240～225Ma)和角闪岩相退变质时代(215～205Ma)一致。对样品含榴黑云母斜长片麻岩(17LSD-1)和含榴云母片岩(18LSD-2)进行锆石Hf同位素分析,获得样品17LSD-1的ε_(Hf)(t)=-23.2～2.8、t_(DM2)~C(Hf)=1712～2845Ma,表明其原岩主要来源于古元古代陆壳重熔;样品18LSD-2的ε_(Hf)(t)=-13.9～8.6、t_(DM2)~C(Hf)=1113～2358Ma,表明样品形成时壳源物质成分占主导地位,同时部分幔源或新生地壳物质的加入,导致少部分ε_(Hf)(t)偏正值。Hf同位素结果表明连三岛变质岩原岩的形成与扬子板块新太古代-早古元古代的陆壳重熔有关。对比前人的相关数据,无论是原岩时代、变质年龄还是变质演化特征,本文研究的连三岛地区片岩/片麻岩与苏鲁造山带的部分变质岩均具有相似的原岩属性和变质属性,因此推断其应归属为苏鲁超高压变质带的一部分,是三叠纪扬子板块向华北板块俯冲碰撞引发的高压-超高压变质事件的产物,不应再作为岩石地层单元划归为"荆山岩群"。  相似文献   

泰青威天然气管道临朐段水毁灾害分布特征与风险评价     

张成信  魏龙飞  唐尧  王艳超  代晓光  任永健 《中国地质调查》2021,8(5):108-114

对泰青威天然气管道临朐段地质灾害发育特征进行调查研究发现,临朐段地质灾害类型主要为水毁灾害,具体可分为坡面水毁、河沟道水毁和台田地水毁。野外地质灾害实地调查临朐段管道沿线共发现地质灾害15处,其中坡面水毁点6处,河沟道水毁点4处,台田地水毁点5处。采用定性与半定量相结合的评价方法对其进行地质灾害风险评价,结果表明: 地质灾害风险等级较高的有1处,占6.66%; 风险等级中等的有4处,占26.67%; 风险等级较低的有10处,占66.67%。根据管道沿线地形地貌、地质灾害发育密度、风险等级等因素,划分地质灾害中易发区61 km,低易发区10 km,管道沿线以地质灾害中易发区为主。最后,针对不同类型、不同风险等级地质灾害提出了相应的防治消减措施,为后期管道安全运营和风险整治决策提供了有效的技术依据。  相似文献   

Geochemical constraints on the distribution of trace elements and volatiles in fluorapatite from the Panasqueira tin-tungsten deposit (Portugal)     

《Chemie der Erde / Geochemistry》2021,81(2):125765

A large, euhedral crystal of fluorapatite (ca. 19.5 × 20.0 mm) from the Panasqueira tin-tungsten deposit (Portugal) was investigated in terms of the distribution of trace elements by using several microanalytical techniques. The studied material represents almost pure fluorapatite with minor amounts of other cations (mainly Sr, Mn, REE and Fe), OH and Cl. Particular interest was given to the distribution of rare earth elements with respect to the crystallographic orientation. A broad range of analytical techniques were used, including optical microscopy coupled with cathodoluminescence imaging, electron probe microanalysis (EPMA), laser ablation – inductively coupled plasma mass spectrometry (LA-ICPMS), Raman microspectroscopy, and simultaneous thermal analysis coupled with mass spectrometry. The investigated crystal consists of the main crystal with a distinct core and rim (Ap_2core and Ap_2rim, respectively), which grew on a previous, euhedral crystal (Ap₁). The fluorapatite demonstrates various types of zoning: regular oscillatory, irregular, and internal sectoring, which is also reflected in trace elements concentrations. The rim Ap_2rim has lower concentrations of Mn, Sr and Fe, and significantly higher concentrations of REE compared to the core Ap_2core and older crystal Ap₁. Furthermore, the rim Ap_2rim is strongly depleted in Th, U and Pb. The entire crystal shows elevated Eu contents, expressed as a strong positive anomaly in chondrite-normalized REE patterns. With regards to the volatiles, F concentrations are constant in Ap₁, Ap_2core and Ap_2rim, whereas Cl is below the EPMA detection limit. The Ap_2rim was the only part of the investigated material containing OH and CO₃, which were observed in the Raman spectra. Furthermore, part of the crystal Ap_2core is extensively altered, likely due to fluid-induced metasomatic processes. LA-ICPMS U-Pb dating yielded highly discordant dates due to common Pb content. A lower intercept age of 297 ± 13 Ma (MSWD = 0.13) indicates the age of the fluorapatite crystallization. The overall analytical data constrain growth and post-growth processes, including crystallization of Ap₁ and Ap_2core, which both have typical hydrothermal Sn-W deposit characteristics, whereas Ap_2rim is related to a carbonate stage of the mineralization in the Panasqueira deposit.  相似文献   

基于镉污染风险的湖南省龙山县百合种植区安全区划     

许青阳  戴亮亮  肖凯琦  彭志刚  巩浩 《地质论评》2023,69(2):2023020010-2023020010

湖南省龙山县作为我国重要的百合生产基地县之一,其土壤却存在一定程度的镉（Cd）污染风险。同时,百合作为一种食药同源的植物,其食用和药用的质量安全标准不一致。因此,在龙山县提出百合种植区安全区划具有重要意义。笔者等在龙山县耕地采集326件表层土壤样品和70件百合样品（配套根系土样）,在分析土壤及百合中Cd的含量和土壤中氧化物、有机质、pH等指标的基础上,探讨Cd生物有效性的影响因素,并据此建立百合Cd生物富集系数预测模型,结合土地质量地球化学调查数据预测耕地的百合Cd含量,给出百合种植区安全区划及建议。结果表明,研究区土壤存在Cd污染风险,百合具有质量安全问题。研究区Cd的生物有效性受到土壤CaO、S、P、K2O含量和土壤pH的共同影响。与多元线性回归模型相比,随机森林模型能够更好地预测百合Cd生物富集系数。百合种植区安全区划显示,研究区食用百合优先种植区、药用百合优先种植区、药用百合次级种植区、结构调整种植区面积占比分别为1. 49%、92. 71%、2. 88%、2. 92%,建议大力开发药用百合农产品。该研究成果将Cd污染风险耕地的安全利用与食药同源农产品的质量安全有效衔接,完善了受污染耕地安全利用的工作方法,为推动龙山县百合产业发展提供了科学依据。  相似文献   

基于镉污染风险的湖南省龙山县百合种植区安全区划     

许青阳  戴亮亮  肖凯琦  彭志刚  巩浩 《地质论评》2023,69(5):1869-1878

湖南省龙山县作为我国重要的百合生产基地县之一,其土壤却存在一定程度的镉(Cd)污染风险。同时,百合作为一种食药同源的植物,其食用和药用的质量安全标准不一致。因此,在龙山县提出百合种植区安全区划具有重要意义。笔者等在龙山县耕地采集326件表层土壤样品和70件百合样品(配套根系土样),在分析土壤及百合中Cd的含量和土壤中氧化物、有机质、pH等指标的基础上,探讨Cd生物有效性的影响因素,并据此建立百合Cd生物富集系数预测模型,结合土地质量地球化学调查数据预测耕地的百合Cd含量,给出百合种植区安全区划及建议。结果表明,研究区土壤存在Cd污染风险,百合具有质量安全问题。研究区Cd的生物有效性受到土壤CaO、S、P、K₂O含量和土壤pH的共同影响。与多元线性回归模型相比,随机森林模型能够更好地预测百合Cd生物富集系数。百合种植区安全区划显示,研究区食用百合优先种植区、药用百合优先种植区、药用百合次级种植区、结构调整种植区面积占比分别为1.49%、92.71%、2.88%、2.92%,建议大力开发药用百合农产品。该研究成果将Cd污染风险耕地的安全利用与食药同源农产品的质量安全有...  相似文献   

Discovery of scandium enrichment and its geological significance in the Dawanshan Neoproterozoic metamorphic basalts from the Mouding area in Central Yunnan Province,ChinaSCIEI北大核心CSCD     

刘兵  周家喜  孙载波  汪方跃  高雅俊  宋冬虎  李小军  关奇 《岩石学报》2023,(10):2968-2984

钪(Sc)是世界各国竞相争夺的关键金属矿产资源之一。滇中牟定大弯山变质玄武岩厚度>36.5m,出露面积0.5km^(2),形成时代为新元古代南华纪(781.3±1.9Ma)。本文对该变质玄武岩开展了全岩地球化学分析、全自动矿物分析(TESCAN TIMA)观测、NPPM薄片区域面扫和单矿物原位LA-ICPMS分析等研究,结果显示变质玄武岩全岩Sc含量为47.0×10^(-6)~97.9×10^(-6),平均含量为69.1×10^(-6),钪氧化物(Sc_(2)O_(3))平均含量为106×10^(-6),变质玄武岩空间Sc矿化特征稳定,具有形成钪矿资源的潜力。同时,变质玄武岩共伴生有钛和铁矿化,全岩TiO_(2)含量为2.57×10^(-2)~6.13×10^(-2),平均为4.25×10^(-2);TFe含量为13.3×10^(-2)~23.7×10^(-2),平均为17.7×10^(-2)。Sc可能存在类质同象和离子相两种赋存形式,类质同象形式Sc主要赋存于钛铁矿和金红石矿物中,钛铁矿中Sc含量为70.0×10^(-6)~168×10^(-6),平均值为108×10^(-6);金红石中Sc含量高达297×10^(-6);而磁铁矿、黑云母等矿物中Sc含量较低,均低于全岩Sc含量,对全岩Sc矿化贡献较小。牟定大弯山Sc矿化与以往报道侵入岩及其风化壳中Sc矿化在富集特征、赋存岩性和载体矿物等方面不同,是变质火山岩中新发现的Sc矿化信息,显示了较好的找矿潜力,对Sc资源勘查和研究具有重要指示意义。  相似文献   

我国海洋功能区划的回顾性评价和新一轮编制建议          下载免费PDF全文

岳奇  朱庆林  刘楠楠  徐伟  董月娥 《海洋开发与管理》2019,36(2):3-7

为完善我国海洋功能区划制度,提高海洋功能区划的编制和实施水平,促进其在我国海洋空间规划乃至国土空间规划中发挥应有作用,文章对我国现行海洋功能区划的实施情况进行回顾性评价,并对新一轮海洋功能区划的编制提出建议。研究结果表明:我国海洋功能区划法律地位高、管控范围广,现行海洋功能区划实施以来,通过建立定量目标管控体系、协调保障行业用海和保护海洋生态环境,对我国海洋经济和海洋生态环境的可持续发展做出巨大贡献;针对实施过程中存在的问题,新一轮海洋功能区划的编制应扩大海洋保护区的规模和种类、提高前瞻性和动态适应性、加强公众实质性参与以及完善技术体系。  相似文献   

Garnet re‐equilibration by coupled dissolution–reprecipitation: evidence from textural,major element and oxygen isotope zoning of ‘cloudy’ garnet     

L. A. J. MARTIN  M. BALLÈVRE  P. BOULVAIS  A. HALFPENNY  O. VANDERHAEGHE  S. DUCHÊNE  E. DELOULE 《Journal of Metamorphic Geology》2011,29(2):213-231

The analysis of texture, major element and oxygen isotope compositions of cloudy garnet crystals from a metapelite sampled on Ikaria Island (Greece) is used to assess the model of growth and re‐equilibration of these garnet crystals and to reconstruct the pressure–temperature–fluid history of the sample. Garnet crystals show complex textural and chemical zoning. Garnet cores (100–200 μm) are devoid of fluid inclusions. They are characterized by growth zoning demonstrated by a bell‐shaped profile of spessartine component (7–3 mol.%), an increase in grossular from 14 to 22 mol.% and δ¹⁸O values between 9.5 ± 0.3‰ and 10.4 ± 0.2‰. Garnet inner rims (90–130 μm) are fluid inclusion‐rich and show a decreasing grossular component from 22 to 5 mol.%. The trend of the spessartine component observed in the inner rim allows two domains to be distinguished. In contrast to domain I, where the spessartine content shows the same trend as in the core, the spessartine content of domain II increases outwards from 2 to 14 mol.%. The δ¹⁸O values decrease towards the margins of the crystals to a lowest value of 7.4 ± 0.2‰. The outer rims (<10 μm) are devoid of fluid inclusions and have the same chemical composition as the outermost part of domain II of the inner rim. Garnet crystals underwent a four‐stage history. Stage 1: garnet growth during the prograde path in a closed system for oxygen. Garnet cores are remnants of this growth stage. Stage 2: garnet re‐equilibration by coupled dissolution–reprecipitation at the temperature peak (630 < T < 650 °C). This causes the creation of porosity as the coupled dissolution–reprecipitation process allows chemical (Ca) and isotopic (O) exchange between garnet inner rims and the matrix. The formation of the outer rim is related to the closure of porosity. Stage 3: garnet mode decreases during the early retrograde path, but garnet is still a stable phase. The resulting garnet composition is characterized by an increasing Mn content in the inner rim’s domain II caused by intracrystalline diffusion. Stage 4: dissolution of garnet during the late retrograde path as garnet is not a stable phase anymore. This last stage forms corroded garnet. This study shows that coupled dissolution–reprecipitation is a possible re‐equilibration process for garnet in metamorphic rocks and that intra‐mineral porosity is an efficient pathway for chemical and isotopic exchange between garnet and the matrix, even for otherwise slow diffusing elements.  相似文献